Thursday, November 12, 2009

Molar Solubility to Ksp

Molar solubility is measured at llbm.

question: Determine the  Ksp of salt AB2 if the molar solubility is
 0.00015 mol/L

1.Write the llbm dissociation rxn.
2. Write the Ksp expression.
3. Set up the ICE chart.
4. Use molar solubility to determine [ion]llbm
5.Sub into Ksp expression.

    AB2 (s)     <=>    A+(aq)   +   2B-(aq)                        Ksp=[A+][B-]2
I    n/a                      0              0
C  n/a
E   n/a                0.00015*        2(0.00015)
* for every mole of A+ that is present at llbm, one mole of AB2 dissolved

Ksp = (0.00015)(0.00030)2
Ksp = 1.4x10-11 for AB2

Sometimes the molar solubility info can be 'hidden':
for example, a saturated solution contains 0.24g of salt per 500mL.
[Use molar mass, convert the given info to mol/L]

Homework:
p486(4)
p493(7,8,9,12)
 ...not all are molar solblty to Ksp, some are Ksp to molar solblty
What would you get if image 1 and  image 2 were combined.

[Ans: a molar solution.]